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Chem Commun (Camb). 2003 Sep 21;(18):2304-5.

Liquid phase oxidation of alcohols with oxygen: in situ monitoring of the oxidation state of Bi-promoted Pd/Al2O3.

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  • 1Institute for Chemical and Bioengineering, Swiss Federal Institute of Technology, ETH Hönggerberg HCI, CH-8093 Zurich, Switzerland.

Abstract

In situ, time-resolved XAS studies on a Bi-Pd/Al2O3 catalyst indicate that Pd, and Bi located on the Pd surface, are in a reduced, metallic state during the oxidation of 1-phenylethanol with molecular oxygen--a key for understanding the role of promoter in the reaction mechanism.

PMID:
14518886
[PubMed]
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