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Bioorg Med Chem Lett. 2003 Mar 24;13(6):1063-6.

alpha-Selective glycosylation with 5-thioglucopyranosyl donors; synthesis of an isomaltotetraoside mimic composed of 5-thioglucopyranose units.

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  • 1The United Graduate School of Agricultural Sciences, Iwate University, Bunkyo-Cho 3, Hirosaki 036-8561, Japan.

Abstract

A general method for alpha-selective glycosylation with 5-thioglucopyranosyl donors followed by efficient deprotection of the resulting products was developed. This methodology was utilized in the synthesis of an isomaltotetraoside analogue.

PMID:
12643912
[PubMed - indexed for MEDLINE]
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