Chem Commun (Camb). 2003 Feb 21;(4):476-7.

Liquid clathrate formation in ionic liquid-aromatic mixtures.

Holbrey JD, Reichert WM, Nieuwenhuyzen M, Sheppard O, Hardacre C, Rogers RD.

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Center for Green Manufacturing and Department of Chemistry, The University of Alabama, Tuscaloosa, AL 35487, USA.

Abstract

1-Alkyl-3-methylimidazolium containing ionic liquids with hexafluorophosphate, bis(trifyl)imide, tetrafluoroborate, and chloride anions form liquid clathrates when mixed with aromatic hydrocarbons; in the system 1,3-dimethylimidazolium hexafluorophosphate-benzene, the aromatic solute could be trapped in the solid state forming a crystalline 2:1 inclusion compound.

PMID:: 12638957; [PubMed]

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