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Chem Commun (Camb). 2003 Jan 7;(1):48-9.

Lactide polymerization by well-defined calcium coordination complexes: comparisons with related magnesium and zinc chemistry.

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  • 1Department of Chemistry, Ohio State University, 100 W. 18th Ave, Columbus, Ohio 43210, USA. chisholm@chemistry.ohio-state.edu

Abstract

Amide and alkoxide coordination complexes of calcium supported by beta-diiminato and bulky trispyrazolylborate complexes are reported together with their activity in lactide ring-opening polymerization; some are amongst the most active systems discovered to date.

PMID:
12610959
[PubMed]
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