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J Am Chem Soc. 2003 Feb 12;125(6):1484-5.

Oxidative heck-type reaction involving cleavage of a carbon-phosphorus bond of arylphosphonic acids.

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  • 1Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 606-8501, Japan.

Abstract

Cleavage of a carbon-phosphorus bond is achieved under palladium catalysis in an oxidative Heck-type reaction which exploits arylphosphonic acids. The reaction of arylphosphonic acids with alkenes provides arylation products in good yields in the presence of TBAF with trimethylamine oxide as an oxidant.

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