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J Am Chem Soc. 2003 Feb 12;125(6):1476-7.

Direct coupling of benzene with olefin catalyzed by Pd(OAc)(2) combined with heteropolyoxometalate under dioxygen.

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  • 1Department of Applied Chemistry, Faculty of Engineering, Kansai University, Suita, Osaka 564-8680, Japan.

Abstract

The oxidative coupling reaction of benzenes with alkenes was successfully achieved by the Pd(OAc)(2)/molybdovanadophosphoric acid (HPMoV)/O(2) system. For example, the reaction of benzene with ethyl acrylate by the above catalytic system in acetic acid afforded ethyl cinnamate as a major product in satisfactory yield.

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