Abstract
The first synthesis of the marine illudalane sesquiterpenoid alcyopterosin E was accomplished through a concise ABC ring-formation strategy using a rhodium(I)-catalysed intramolecular alkyne cyclotrimerisation as key connection.
MeSH terms
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Anthozoa / chemistry
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Cyclization
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Sesquiterpenes / chemical synthesis*
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Sesquiterpenes / chemistry
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Sesquiterpenes / isolation & purification
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Stereoisomerism
Substances
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Sesquiterpenes
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alcyopterosin A
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alcyopterosin E