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Org Lett. 2002 Nov 28;4(24):4297-300.

Regio- and chemoselective catalytic transfer hydrogenation of aromatic nitro and carbonyl as well as reductive cleavage of azo compounds over novel mesoporous NiMCM-41 molecular sieves.

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  • 1Department of Chemistry, Indian Institute of Technology-Bombay, Powai, Mumbai 400 076, India.

Erratum in

  • Org Lett. 2003 Jan 23;5(2):233..

Abstract

[reaction: see text] [corrected] Regio- and chemoselective reduction of nitroarenes and carbonyl compounds and reductive cleavage of azo compounds, including bulkier molecules, was achieved by the catalytic transfer hydrogenation method (CTH) using a novel nickel-containing mesoporous silicate (NiMCM-41) molecular sieve catalyst. In addition, the catalyst was also found to behave as a truly heterogeneous catalyst as the yield was practically unaffected.

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