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Chem Commun (Camb). 2002 May 7;(9):950-1.

Photo-induced ligand substitution at a remote site via electron transfer in a porphyrin-appended rhenium carbonyl supermolecule.

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  • 1Department of Chemistry, University of York, York, UK YO10 5DD.

Abstract

The photochemical and electrochemical properties of a Zn-porphyrin appended rhenium(I) tricarbonyl bipyridine 3-Me-pyridine complex have been investigated; visible-light sensitisation of electron transfer results in ligand substitution at a site remote from the chromophore.

PMID:
12123063
[PubMed - indexed for MEDLINE]
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