Abstract
Starting from ergosterol two novel 9,11-secosterols with modified side chains (1a) and (1c) were synthesized via eight main transformations.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Animals
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Candida / enzymology
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Cell Cycle / drug effects
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Chromatography, Thin Layer
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Cnidaria / chemistry*
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Enzymes, Immobilized
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Fungal Proteins
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Lipase / metabolism
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Mass Spectrometry
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Molecular Structure
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Nuclear Magnetic Resonance, Biomolecular
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Secosteroids / chemical synthesis
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Secosteroids / chemistry
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Secosteroids / isolation & purification*
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Spectrophotometry, Infrared
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Spectrophotometry, Ultraviolet
Substances
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24-nor-9,11-seco-11-acetoxy-3,6-dihydroxycholesta-7,22-dien-9-one
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24-nor-9,11-seco-11-oxo-3,6-dihydroxycholesta-7,22-dien-9-one
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Enzymes, Immobilized
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Fungal Proteins
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Secosteroids
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Novozyme 435
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Lipase