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Org Lett. 2001 Jun 28;3(13):1985-7.

Photoinduced formation of beta-oxy-alpha,alpha-disubstituted-alpha-amino acid derivatives from ketoximes.

Author information

  • 1Departamento de Química Orgánica y Unidad Asociada al CSIC Universidad de Santiago de Compostela, 15782 Santiago de Compostela, Spain.

Abstract

[reaction: see text] The first intermolecular radical addition onto ketoxime ethers is described. beta-Oxygenated quaternary alpha-amino acid derivatives IotaIota were obtained upon irradiation of alpha-alkoxycarbonyl ketoxime ethers Iota in the presence of suitable alpha-alkoxy carbon radical precursors and a sensitizer.

PMID:
11418030
[PubMed - indexed for MEDLINE]
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