Display Settings:

Format

Send to:

Choose Destination
Org Lett. 2000 Jul 13;2(14):2135-8.

Synthesis of glycosyl-1-phosphates via dehydrative glycosylation.

Author information

  • 1Department of Chemistry, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, USA.

Erratum in

  • Org Lett 2000 Oct 19;2(21):3411.

Abstract

[reaction: see text] Direct synthetic access to glycosyl-1-phosphates is accomplished with the dehydrative coupling of carbohydrate hemiacetals and dialkyl phosphates, employing dibenzothiophene-5-oxide and triflic anhydride. The procedure offers a new and versatile method for efficient preparation of a host of glycosyl-1-phosphates of variable structure with good control over anomeric selectivity.

PMID:
10891249
[PubMed - indexed for MEDLINE]
PubMed Commons home

PubMed Commons

0 comments
How to join PubMed Commons

    Supplemental Content

    Full text links

    Icon for American Chemical Society
    Loading ...
    Write to the Help Desk