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Org Lett. 2000 Mar 9;2(5):691-3.

Segregation of separate steps in chromium-catalyzed reactions for convenience and mechanistic analysis

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  • 1Department of Chemistry, University of Rochester, New York 14627, USA.


[structure: see text] We have developed an apparatus for carrying out redox-coupled chromium-manganese or chromium-zinc reactions on solid-supported substrates which allows recycling of the stoichiometric reductant. In addition to providing a greatly simplified procedure for these reactions, we observe striking differences in the recyclability of Mn and Zn. A preliminary extension of the methodology to the catalytic coupling of allylchromium reagents with solid-supported aldehydes is also reported.

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