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Significant structure theory applied to liquid 4He *Department of Chemistry, Korea Advanced Institute of Science, Seoul, Korea †Department of Chemistry, University of Utah, Salt Lake City, Utah 84112 This article has been cited by other articles in PMC.Abstract The large kinetic zero-point motion of 4He molecules has been properly taken into account in the significant structure theory of liquids in order to describe the liquidity of liquid 4He. The Debye and the Bose-Einstein partition functions are used for the solid-like molecules of the normal fluid component and for the whole gas-like molecules, respectively. The solid-like molecules of the superfluid component are considered as ground state molecules without having positional degeneracies. The Bragg-Williams approximation of an order/disorder phase transition has been applied to the λ transition of liquid 4He. Thermodynamic and surface properties of liquid 4He have been calculated up to the critical point. The results are satisfactory when compared with the observed values. Full text Full text is available as a scanned copy of the original print version. Get a printable copy (PDF file) of the complete article (795K), or click on a page image below to browse page by page. Links to PubMed are also available for Selected References. Selected References These references are in PubMed. This may not be the complete list of references from this article.
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